μ-4,4′-Bipyridine-κ2 N:N′-bis­[aqua­(4,4′-bi­pyridine-κN)(l-valinato-κ2 N,O)copper(II)] dinitrate dihydrate

نویسندگان

  • Ben-Yong Lou
  • Mao-Chun Hong
چکیده

In the title dinuclear complex, [Cu(2)(C(5)H(10)NO(2))(2)(C(10)H(8)N(2))(3)(H(2)O)(2)](NO(3))(2)·2H(2)O, each of the two l-valinate anions chelates a Cu(II) center through the amino N and carboxyl-ate O atom, forming a five-membered ring. A 4,4'-bipyridine mol-ecule bridges two water-coordinated Cu atoms, each of which is connected to another 4,4'-bipyridine, giving rise to a square-pyramidal coordination geometry for the Cu(II) centers. The dinuclear dications, nitrate anions and uncoord-inated water mol-ecules are linked into a two-dimensional structure.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008